If it's an electric steamer don't fill it, there will be an optimum water measure, mine is 90 mil which takes 15mins or so to boil off and stop. Your tyres may need more than 1 go but I would let them cool in between and peal as much as you can with your fingers while they cool.
No expert, it doesn't always work perfectly but has helped me out a few times and saved me a few quid.
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