Hi, what bike are they going on? Reason for asking is that one appears to be a 700c tyre (road or cyclocross bike) and the other is 26" (mountain bike).
Not done that ride so any info would be great to try and narrow down your tyre choice, do you know how much on road riding will be involved and what the off road riding will be like, singletrack, fireroad, cycle paths etc?
Lack of grip, punctures or tyres which are too heavy or sluggish for a long distance sportive style ride can make things hard work so the more info the better
Cheers
Adam