Just to sort of back up what Kayce said above, if you do need to put a lighter colour down before a darker one, back it with white, that will give the colour it's brilliance. Then back that with silver, this is completely opaque and nothing will come through it, so you can put black down afterwards safe in the knowledge your colour is protected.
Be warned though the build from Faskolor / createx / auto air - ( they're all the same ) is much higher than from the thinner based type paints like Pactra, you design will start to get a bit '3D' after a few colours so backing with silver as I've mentioned above will increase this.
The design should still be okay from the outside though.
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