I imagine the "voltage" that you're adjusting will be the charger's "peak cut-off", and not the nominal voltage of the pack as all LiPo cells are 3.7V at rest. You might want to set the cut-off lower sometimes for storage, which is why the setting is there...but in this case, you want 4.2V per cell. A charging bag is always a good idea as Bodgit pointed out, and 3.3A charge rate will be perfect for your pack.
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Nah you can put 10 volts in your lipos and not cause any bother. But just leave it on 8.4, C is the unit of charge in coulombs.
One coulomb is the amount of electric charge transported in one second by a steady current of one ampere.
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You can put 10V into a 2S pack if you have a strong desire for 3rd degree burns and to set the building alight, but short of that, it's a VERY bad idea.